ICI PAINTS -- GLASS FROSTING SPRAY, ZY0152 MATERIAL SAFETY DATA SHEET NSN: 801000N088387 Manufacturer's CAGE: 01PD6 Part No. Indicator: A Part Number/Trade Name: GLASS FROSTING SPRAY, ZY0152 =========================================================================== General Information =========================================================================== Company's Name: ICI PAINTS Company's Street: 925 EUCLID AVE Company's City: CLEVELAND Company's State: OH Company's Country: US Company's Zip Code: 44115 Company's Emerg Ph #: 800-545-2643 Company's Info Ph #: 800-545-2643 Safety Data Action Code: A Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 08MAY97 Safety Data Review Date: 31JUL98 MSDS Serial Number: CHLZK =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: METHANE OXYBIS- Ingredient Sequence Number: 01 Percent: 50-60 Ingredient Action Code: A NIOSH (RTECS) Number: PM4780000 CAS Number: 115-10-6 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: SILICA, AMORPHOUS, PRECIPITATED AND GEL; (SILICA, GEL, AMORPHOUS). LD50: (ORAL, RAT) 10 G/KG. Ingredient Sequence Number: 02 Percent: 1-5 Ingredient Action Code: A NIOSH (RTECS) Number: VV7315000 CAS Number: 112926-00-8 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM). LD50: (ORAL, RAT) 8 ML/KG. Ingredient Sequence Number: 03 Percent: 5-10 Ingredient Action Code: A NIOSH (RTECS) Number: 1003161VN CAS Number: 64742-89-8 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO Ingredient: TOLUENE (SARA 313) (CERCLA). LD50: (ORAL, RAT) 5000 MG/KG. Ingredient Sequence Number: 04 Percent: 30-40 Ingredient Action Code: A NIOSH (RTECS) Number: XS5250000 CAS Number: 108-88-3 OSHA PEL: 200 PPM ACGIH TLV: 50 PPM, S ------------------------------------- Proprietary: NO Ingredient: BENZENE (SARA 313) (CERCLA) % WT: 0.01-0.1 Ingredient Sequence Number: 05 Percent: <0.1 Ingredient Action Code: A NIOSH (RTECS) Number: CY1400000 CAS Number: 71-43-2 OSHA PEL: N/K (FP N) ACGIH TLV: 10 PPM ------------------------------------- Proprietary: NO Ingredient: ACRYLIC COPOLYMER Ingredient Sequence Number: 06 Percent: 5-10 Ingredient Action Code: A NIOSH (RTECS) Number: 1005957AC CAS Number: 25608-33-7 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------------- Proprietary: NO TOLUENE APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO (ING 8) Ingredient Sequence Number: 07 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 7: HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & (ING 9) Ingredient Sequence Number: 08 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 8: EXPOS INFO (FP N). SUPPLEMENTAL HEALTH INFO: OTHER EFTS OF OVEREXP MAY INCL TOXICITY TO LIVER, KIDNEY, (ING 10) Ingredient Sequence Number: 09 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO REPORTS HAVE ASSOC RPTD & PRLNGD OCCUP OVEREXP TO (ING 11) Ingredient Sequence Number: 10 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 10: SOLVS W/PERM BRAIN & NERVOUS SYSTEM DMG. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS MAY BE (ING 12) Ingredient Sequence Number: 11 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 11: HARMFUL/FATAL. DELIB INHAL OF TOLUENE HAS BEEN ASSOC W/NEONATAL EFTS IN HUMANS. DEVELOPMENTAL TOXICITY (ING 13) Ingredient Sequence Number: 12 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 12: HAS ALSO BEEN DEMONSTRATED IN LAB ANIMALS EXPOSED TO TOLUENE BY INHAL. ADDNLY, DELIB INHAL OF TOLUENE (ING 14) Ingredient Sequence Number: 13 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 13: MAY RSLT IN CARD SENSIT WHICH CAN CAUSE IRREGULAR HEART RHYTHM & SUDDEN DEATH. Ingredient Sequence Number: 14 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: FIRST AID PROC: WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15 MIN. IF IRRIT OR OTHER EFTS PERSIST, OBTAIN MED (ING 16) Ingredient Sequence Number: 15 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 15: TREATMENT. INGEST: IF SWALLOWED, OBTAIN MED TREATMENT IMMEDIATELY. Ingredient Sequence Number: 16 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: SPILL PROC: PROPER CONTAINER. COMPLETE PERSONAL PROT EQUIP MUST BE USED DURING CLEANUP. LARGE SPILLS: SHUT OFF (ING 18) Ingredient Sequence Number: 17 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 17: LEAK IF SAFE TO DO SO. DIKE & CONTAIN SPILL. PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORB TO PICK UP (ING 19) Ingredient Sequence Number: 18 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 18: EXCESS RESIDUE. KEEP SALVAGEABLE MATL & RINSE WATER OUT OF SEWERS & WATER COURSES. SMALL SPILLS: USE (ING 20) Ingredient Sequence Number: 19 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 19: ABSORB TO PICK UP RESIDUE & DISPOSE OF PROPERLY. Ingredient Sequence Number: 20 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: OTHER PRECS: NOT IN USE. AVOID CNDTNS WHICH RSLT IN FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING OR (ING 22) Ingredient Sequence Number: 21 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 21: ABRADING (SANDING) PAINTED SURFS. IF SUCH CNDTNS CANNOT BE AVOIDED, USE APPROP NIOSH APPRVD RESP PROT (ING 23) Ingredient Sequence Number: 22 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 22: AS DIRECTED UNDER SPECIAL PROT INFO. EMPTY CNTNRS MAY CONTAIN HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN (ING 24) Ingredient Sequence Number: 23 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ------------------------------------- Proprietary: NO Ingredient: ING 23: TRANSFERRING TO PREVENT ACCUMULATION OF STATIC CHARGE. Ingredient Sequence Number: 24 Ingredient Action Code: A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: LIQUID. Boiling Point: >176F,>80C Specific Gravity: 0.752 Percent Volatiles By Volume: 96.03 =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: 1F,-17C Lower Explosive Limit: 3.4% Upper Explosive Limit: 18.0% Extinguishing Media: DRY CHEMICAL OR FOAM. WATER FOG. CARBON DIOXIDE. Special Fire Fighting Proc: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire And Expl Hazrds: CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT OR FIRE. VAPS MAY IGNITE EXPLOSIVELY AT AMBIENT TEMPS. VAPS ARE HVR/AIR & MAY TRAVEL LONG DISTS (SUPDAT) =========================================================================== Reactivity Data =========================================================================== Stability: YES Cond To Avoid (Stability): CAN FORM EXPLOSIVE PEROXIDES ON LONG STANDING IN AIR. AVOID ELEVATED TEMPS. CONTACT W/OXIDIZING AGENTS, CONTAM (SUPDAT) Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES, VINYL POLYMERS. Hazardous Decomp Products: CARBON MONOXIDE, CARBON DIOXIDE. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT =========================================================================== Health Hazard Data =========================================================================== LD50-LC50 Mixture: SEE INGREDIENTS Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: INHAL: IRRIT OF RESP TRACT. PRLNGD INHAL MAY LEAD TO FATG, DROW, DIZZ &/OR LT HEAD, HDCH, UNCOORD, NAUS, COUGH, CNS DEPRESS, RESP PROBS, INTOXICATION, CONFUSION, ANESTH EFT OR NARCOSIS, DFCLTY BRTHG, CARD ABNORMS, LOSS OF CONSCIOUSNESS, RESP FAILURE, ASPHYXIATION, DEATH. SKIN CONTACT: IRRIT OF SKIN. (EFTS OF OVEREXP) Carcinogenicity - NTP: YES Carcinogenicity - IARC: YES Carcinogenicity - OSHA: YES Explanation Carcinogenicity: BENZENE: IARC MONO, SUPP, VOL 7, PG 120, 1987:GROUP 1. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:KNOWN TO BE (SUPDAT) Signs/Symptoms Of Overexp: HLTH HAZ: PRLNGD/RPTD CONTACT CAN CAUSE DERM, IRRIT. PRLNGD/RPTD CONTACT CAN CAUSE BLURRED VISION, TEARING, REDNESS, SEVERE IRRIT, CORNEAL INJURY. INGEST: MAY CAUSE LUNG INFLAM & DAMAGE DUE TO ASPIR OF MATL INTO LUNGS, NAUSEA, VOMIT, (ING 7) Med Cond Aggravated By Exp: EYE, SKIN, RESPIRATORY DISORDERS. ASTHMA- LIKE CONDITIONS. CARDIAC ABNORMALITIES. KIDNEY DISORDERS. LIVER DISORDERS. NERVOUS SYSTEM DISORDERS. Emergency/First Aid Proc: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET MED HELP FOR ANY BRTHG DFCLTY. GET MED ATTN IF DISCOMFORT OR IRRIT PERSISTS. SKIN: FLUSH FROM SKIN W/WATER. THEN WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAM CLTHG. WASH CONTAM CLTHG BEFORE REUSE. IF IRRIT OCCURS, CONSULT MD. EYES: FLUSH IMMED W/LARGE AMTS OF (ING 15) =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: COMPLY W/ALL APPLICABLE HEALTH & ENVIRONMENTAL REGS. ELIMINATE ALL SOURCES OF IGNIT. VENT AREA. VENT AREA W/ EXPLOSION-PROOF EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATLS. USE NON-SPKG TOOLS. EVACUATE ALL UNNEC PERS. PLACE COLLECTED MATL IN (ING 17) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. Precautions-Handling/Storing: STORE BELOW 80F(27C). KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. Other Precautions: USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN & EYES & BRTHG OF VAPS. WASH HANDS THOROUGHLY AFTER HNDLG, ESP BEFORE EATING OR SMOKING. KEEP CNTNRS TIGHTLY CLOSED & UPRIGHT WHEN (ING 21) =========================================================================== Control Measures =========================================================================== Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation: PROVIDE DILUTION VENT OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPS. USE EXPLOSION-PROOF EQUIP. USE NON-SPARKING EQUIP. Protective Gloves: IMPERVIOUS GLOVES. Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). IMPERVIOUS CLOTHING, FACE SHIELD. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Suppl. Safety & Health Data: EXPLO HAZ: TO SOURCE OF IGNIT & FLASH BACK. MAY DECOMPOSE UNDER FIRE CONDITIONS EMITTING IRRITANT &/OR TOXIC GASES. CNDTNS TO AVOID: W/ORGANIC PEROXIDES, CONTACT W/OXIDIZABLE MATLS, SPARKS, OPEN FLAME, IGNITION SOURCES. EXPLAN OF CARCIN: CARCIN. OSHA REGULATED: CFR 29 1910.1028. =========================================================================== Transportation Data =========================================================================== =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: YES Technical Review Date: 30JUL98 Label Date: 06JUL98 Label Status: M Common Name: GLASS FROSTING SPRAY, ZY0152 Chronic Hazard: YES Signal Word: DANGER! Acute Health Hazard-Moderate: X Contact Hazard-Moderate: X Fire Hazard-Severe: X Reactivity Hazard-None: X Special Hazard Precautions: FLAMMABLE. ACUTE: INHAL: RESP TRACT IRRIT, FATG, DROW, DIZZ &/OR LT HEAD, HDCH, UNCOORD, NAUS, COUGH, CNS DEPRESS, RESP PROBS, INTOXICATION, CONFUSION, ANESTH EFT OR NARCOSIS, DFCLTY BRTHG, CARD ABNORMS, UNCON, RESP FAILURE, ASPHYX, DEATH. SKIN: IRRIT, DERM, DEFAT. CONTACT W/LIQ DIMETHYL ETHER MAY CAUSE FREEZING OF SKIN. EYES: IRRIT, BLURRED VISION, TEARING, REDNESS, CORNEAL INJURY. INGEST: LUNG INFLAM & DMG DUE TO ASPIR, NAUS, VOMIT, DIARR, GI DISTURBS, CNS DEPRESS. CHRONIC: CANCER HAZARD. CONTAINS BENZENE WHICH IS LISTED AS A HUMAN BLOOD CARCIN (FP N). TOLUENE APPEARS ON THE NAVY OCCUP CHEM REPRO HAZS LIST (FP N). Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: ICI PAINTS Label Street: 925 EUCLID AVE Label City: CLEVELAND Label State: OH Label Zip Code: 44115 Label Country: US Label Emergency Number: 800-545-2643