MALLINCKRODT BAKER, INC -- ACETIC ACID GLACIAL, V194 -- 6810-00N086671
=====================  Product Identification  =====================

Product ID:ACETIC ACID GLACIAL, V194
MSDS Date:09/08/1997
FSC:6810
NIIN:00N086671
=== Responsible Party ===
Company Name:MALLINCKRODT BAKER, INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC)
CAGE:HO851
=== Contractor Identification ===
Company Name:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:HO851
Company Name:MALLINCKRODT BAKER,  INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829

=============  Composition/Information on Ingredients  =============

Ingred Name:ACETIC ACID (CERCLA)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 100%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:EFTS OF OVEREXP: CHRONIC: REPEATED/PROLONGED EXPOS MAY
    CAUSE DARKENING OF SKIN, EROSION OF EXPOSED FRONT TEETH, (ING 3)
RTECS #:9999999ZZ

Ingred Name:ING 2: & CHRONIC INFLAMMATION OF THE NOSE, THROAT, AND
    BRONCHIAL TUBES.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: EYES: IMMEDIATELY FLUSH WITH PLENTY OF
    WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER AND UPPER (ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4: EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION
    IMMEDIATELY.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: & PLACE IN CHEM WASTE CONTR. USE NON-SPKG TOOLS
    & EQUIP. DO NOT USE COMBUST MATLS, SUCH AS SAWDUST. (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6: DO NOT FLUSH TO SEWER! US REGS (CERCLA) REQUIRE
    REPORTING SPILLS & RELEASES TO SOIL, WATER & AIR IN (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: EXCESS OF REPORTABLE QTYS. THE TOLL FREE NUMBER FOR
    US COAST GUARD NATIONAL RESPONSE CENTER IS (800) 424-8802.
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH: DISPOSE OF CONTAINER AND UNUSED PRODUCT IN
    ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: STORE ABOVE 63F (17C). CONTAINERS MAY BE
    HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: (VAPORS, LIQUID); OBSERVE ALL WARNINGS AND
    PRECAUTIONS LISTED FOR THE PRODUCT.
RTECS #:9999999ZZ

Ingred Name:RESP PROT: EXPOSURE LEVELS ARE NOT KNOWN, USE A
    FULL-FACEPIECE POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR. (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: WARNING: AIR PURIFYING RESPIRATORS DO NOT PROTECT
    WORKERS IN OXYGEN-DEFICIENCY ATMOSPHERES.
RTECS #:9999999ZZ

Ingred Name:VENT: PREF BECAUSE IT CAN CTL EMISSIONS OF CONTAMINANT AT
    ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: AREA. PLEASE REFER TO ACGIH DOCUMENT, INDUS VENT, A
    MANUAL OF REC PRACTICES, MOST RECENT EDITION, FOR DETAILS.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 (ORAL RAT): 3310 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: CONCENTRATED VAPS MAY
    CAUSE SERIOUS DMG TO LINING OF NOSE, THROAT, & LUNGS. BRTHG DFCLTYS
    MAY OCCUR. NEITHER ODOR NOR DEGREE OF IRRIT ARE ADEQ TO INDICATE
    VAP CONC. INGEST: CAN CAUSE SEV  INJURY LEADING TO DEATH. SYMPS
    INCL SORE THROAT, VOMIT, & DIARR. INGEST OF AS LITTLE AS 1.0 ML HAS
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: RESULTED IN PERFORATION OF ESOPHAGUS.
    SKIN: CONCENTRATED SOLUTION MAY CAUSE SERIOUS DMG. EFTS MAY INCL
    REDNESS, PAIN, BURNS. HIGH VAP CONCS MAY CAUSE SENSIT. EYES:
    CONCENTRATED SOLUTIONS MAY	CAUSE SEV DMG FOLLOWED BY LOSS OF
    SIGHT. EXPOS TO VAP MAY CAUSE INTENSE WATERING & IRRIT. (ING 2)
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING SKIN
    DISORDERS OR EYE PROBLEMS, OR IMPAIRED RESPIRATORY FUNCTION MAY BE
    MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTIFICIAL
    RESP. IF BRTHG IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST: DO NOT
    INDUCE VOMIT! GIVE LARGE QUANTITIES OF WATER/MILK IF AVAILABLE.
    NEVER GIVE A NYTHING BY MOUTH TO AN UNCON PERSON. GET MED ATTN
    IMMED. SKIN: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN
    WHILE REMOVING CONTAM CLTHG & SHOES. WASH CLTHG BEFORE REUSE. CALL
    MD. (ING 4)

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Flash Point:104F,40C
Lower Limits:4.0%
Upper Limits:16.0%
Extinguishing Media:WATER, DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER
    SPRAY MAY BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
    WATER MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOS & TO DILUTE
    SPILLS TO NON-FLAM MIXTS. WATER-DILUTED (SUP DAT)
Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAP-AIR MIXTS ARE
    EXPLO W/IN FLAM LIMS NOTED ABOVE. VAPS CAN FLOW ALONG SURFS TO
    DISTANT IGNIT SOURCE & FLASH BACK. CONT W/STRONG (SUP DAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENT AREA. REMOVE ALL SOURCES OF IGNIT. WEAR
    APPROP PERS PROT EQUIP. ISOLATE HAZ AREA. KEEP UNNEC & UNPROT PERS
    FROM ENTERING. USE WATER SPRAY TO DILUTE SPILL TO NON-FLAM MIXT.
    CONTAIN & RECOVER W/INE RT MATL (VERMICULITE, DRY SAND, EARTH),(ING
    6)
Neutralizing Agent:JT BAKER NEUTRASORB(TM) OR TEAM(M) 'LOW NA+' ACID
    NEUTRALIZERS ARE RECOMMENDED.

======================	Handling and Storage  ======================

Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DMG. STORE IN
    COOL, DRY, WELL-VENTD LOCATION, AWAY FROM ANY AREA WHERE FIRE HAZ
    MAY BE ACUTE. OUTSIDE/DETACHED STOR IS PREF.
Other Precautions:SEPARATE FROM INCOMPATIBLES. CONTRS SHOULD BE BONDED
    & GROUNDED FOR TRANSFERS TO AVOID STATIC SPARKS. STOR & USE AREAS
    SHOULD BE NO SMOKING AREAS. USE NON-SPARKING TYPE TOOLS & EQUIP,
    INCL EXPLO-PROOF  VENT. PROTECT FROM FREEZING. (ING 10)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD FULL
    FACEPIECE RESP W/ORG VAP CARTRIDGE MAY BE WORN UP TO 50 TIMES EXPOS
    LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP
    SUPPLIER, WHICHEVER IS LOW EST. FOR EMER/INSTANCES WHERE (ING 12)
Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
    BELOW AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS GEN (ING 14)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
    WEAR IMPERVIOUS PROT CLOTHING, INCL BOOTS, LAB COAT,
    APRON/COVERALLS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH: 2.4 (1.0M SOLN). FIRE FIGHT PROC: ACID CAN REACT W/METALS TO FORM
    HYDROGEN GAS. EXPLO HAZ: OXIDIZERS MAY CAUSE FIRE. REACTS W/MOST
    METALS TO PRDCE HYDROGEN GAS, WHICH CAN FORM EXPLO MIXT W/AIR. FL
    AM LIQ & VAP! CNDTNS TO AVOID: FREEZINGWHICH MAY CAUSE CONTR TO
    BURST. MATLS TO AVOID: HYDROXIDES, OXIDES, PHOSPHATES.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:63.0F,17.2C
Vapor Pres:11 @ 20C
Vapor Density:2.1
pH:SUPDAT
Evaporation Rate & Reference:0.97 (BUTYL ACETATE=1)
Solubility in Water:INFINITELY SOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH STRONG, VINEGAR-LIKE
    ODOR
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, MOST METALS, CHROMIC ACID, SODIUM PEROXIDE, NITRIC ACID,
    STRONG CAUSTICS, HEAT, FLAME, CARBONATES, (SUP DAT)
Stability Condition to Avoid:HEAT, SUNLIGHT, WATER, FLAME, IGNIT
    SOURCES, FREEZING, INCOMPATIBLES. ACETIC ACID CONTRACTS SLIGHTLY
    UPON (SUP DAT)
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY
    FORM WHEN HEATED TO DECOMPOSITION. MAY ALSO RELEASE TOXIC AND
    IRRITATING VAPORS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
    SHOULD BE HANDLED AS HAZ WASTE & SENT TO RCRA APPRVD WASTE
    FACILITY. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE
    MANAGEMENT OPTIONS. STATE & LO C DISP REGS MAY DIFFER FROM FED
    REGS. (ING 9)

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 disclaims all liability for its use.  Any person utilizing this
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