Material Safety Data Sheet
Iron (III) Nitrate Nonahydrate

ACC# 09780
Section 1 - Chemical Product and Company Identification

MSDS Name: Iron (III) Nitrate Nonahydrate
Catalog Numbers: S74199, S74200, I110 100, I110 3, I110 500, I110-100, I110-3, I110-500, I110100, I1103, I110500, NC9483480, NC9483494
Synonyms:
Ferric nitrate nonahydrate, Nitric acid iron (3+) salt nonahydrate.
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7782-61-8 Iron (III) Nitrate Nonahydrate >98 unlisted

Hazard Symbols:
XI O
Risk Phrases:
36/37/38 8

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: light purple. Danger! Oxidizer. May cause severe respiratory and digestive tract irritation with possible burns. May cause severe skin irritation and possible burns. May cause central nervous system effects. May cause cardiac disturbances. May cause liver and kidney damage. May cause blood abnormalities.
Target Organs: Blood, kidneys, heart, central nervous system, liver.


Potential Health Effects
Eye: Contact with eyes may cause severe irritation, and possible eye burns.
Skin: May cause severe skin irritation. May cause skin burns.
Ingestion: May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause cardiac disturbances.
Inhalation: May cause respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea (labored breathing), and death.
Chronic: May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate, unconsciousness and possible death.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.
Antidote: The use of Deferoxamine as a chelating agent should be determined only by qualified medical personnel.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Oxidizer. Greatly increases the burning rate of combustible materials.
Extinguishing Media: Use water only! Do NOT use carbon dioxide or dry chemical.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Wear a self contained breathing apparatus and appropriate Personal protection. (See Exposure Controls, Personal Protection section). Sweep up, then place into a suitable container for disposal.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get on skin or in eyes. Do not ingest or inhale. Keep away from clothing and other combustible materials.
Storage: Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Iron (III) Nitrate Nonahydrate none listed none listed none listed

OSHA Vacated PELs: Iron (III) Nitrate Nonahydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: light purple
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Vapor Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: 257 deg F
Freezing/Melting Point:117 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:100 deg C
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Soluble in water.
Specific Gravity/Density:1.6840 (water)
Molecular Formula:FeN3O9.9H2O
Molecular Weight:403.9823

Section 10 - Stability and Reactivity


Chemical Stability: Stable. However, may decompose if heated.
Conditions to Avoid: Incompatible materials, temperatures above 50�C.
Incompatibilities with Other Materials: Combustible materials, reducing agents, strong oxidizing agents, light.
Hazardous Decomposition Products: Nitrogen oxides.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:
CAS# 7782-61-8: NO7175000
LD50/LC50:
CAS# 7782-61-8:
Oral, rat: LD50 = 3250 mg/kg;
Carcinogenicity:
CAS# 7782-61-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: None.

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information reported.
Physical: No information available.
Other: None.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: FERRIC NITRATE FERRIC NITRATE
Hazard Class: 5.1 5.1(9.2)
UN Number: UN1466 UN1466
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 7782-61-8 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7782-61-8: acute, flammable, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7782-61-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI O
Risk Phrases:

R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 8 Contact with combustible material may cause
fire.

Safety Phrases:

S 17 Keep away from combustible material.
S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)

CAS# 7782-61-8: 1
Canada
Canada

None of the chemicals in this product are listed on the DSL or NDSL list. This product has a WHMIS classification of C, D2B.
CAS# 7782-61-8 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7782-61-8: OEL-DENMARK:TWA 1 mg(Fe)/m3 JANUARY 1993 OEL-FINLA
ND:TWA 1 mg(Fe)/m3 JANUARY 1993 OEL-THE NETHERLANDS:TWA 1 mg(Fe)/m3
JANUARY 1993 OEL-SWITZERLAND:TWA 1 mg(Fe)/m3 JANUARY 1993 OEL-UNIT
ED KINGDOM:TWA 1 mg(Fe)/m3;STEL 2 mg(Fe)/m3 JANUARY 1993

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #1 Date: 8/02/2000
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.