Material Safety Data
Sheet
Iron (III) Nitrate Nonahydrate
ACC# 09780
Section 1 - Chemical Product and Company
Identification |
MSDS Name: Iron (III) Nitrate
Nonahydrate
Catalog Numbers: S74199, S74200, I110 100, I110
3, I110 500, I110-100, I110-3, I110-500, I110100, I1103, I110500, NC9483480,
NC9483494
Synonyms: Ferric nitrate nonahydrate, Nitric acid iron (3+)
salt nonahydrate.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
Section 2 -
Composition, Information on Ingredients |
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7782-61-8 |
Iron (III) Nitrate Nonahydrate |
>98 |
unlisted
|
Hazard Symbols: XI O
Risk
Phrases: 36/37/38 8
Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: light purple. Danger! Oxidizer. May cause
severe respiratory and digestive tract irritation with possible burns. May cause
severe skin irritation and possible burns. May cause central nervous system
effects. May cause cardiac disturbances. May cause liver and kidney damage. May
cause blood abnormalities.
Target Organs: Blood, kidneys,
heart, central nervous system, liver.
Potential Health
Effects
Eye: Contact with eyes may cause
severe irritation, and possible eye burns.
Skin: May cause
severe skin irritation. May cause skin burns.
Ingestion:
May cause central nervous system depression, kidney damage, and liver damage.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May
cause cardiac disturbances.
Inhalation: May cause
respiratory tract irritation. May cause methemoglobinemia, cyanosis,
convulsions, tachycardia, dyspnea (labored breathing), and death.
Chronic: May cause methemoglobinemia, which is
characterized by chocolate-brown colored blood, headache, weakness, dizziness,
breath shortness, cyanosis (bluish skin due to deficient oxygenation of blood),
rapid heart rate, unconsciousness and possible death.
Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid.
Skin: Get medical aid. Immediately flush skin
with plenty of soap and water for at least 15 minutes while removing
contaminated clothing and shoes.
Ingestion: If victim is
conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid
immediately.
Inhalation: Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.
Antidote: The use of Deferoxamine as a chelating agent
should be determined only by qualified medical personnel.
Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Use water spray to keep fire-exposed containers cool. Oxidizer. Greatly
increases the burning rate of combustible materials.
Extinguishing
Media: Use water only! Do NOT use carbon dioxide or dry chemical.
Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Wear a self contained breathing
apparatus and appropriate Personal protection. (See Exposure Controls, Personal
Protection section). Sweep up, then place into a suitable container for
disposal.
Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Remove
contaminated clothing and wash before reuse. Use with adequate ventilation. Do
not get on skin or in eyes. Do not ingest or inhale. Keep away from clothing and
other combustible materials.
Storage: Do not store near
combustible materials. Store in a tightly closed container. Store in a cool,
dry, well-ventilated area away from incompatible substances.
Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
Iron (III) Nitrate Nonahydrate |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Iron
(III) Nitrate Nonahydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate protective gloves to
prevent skin exposure.
Clothing: Wear appropriate
protective clothing to prevent skin exposure.
Respirators: Follow the
OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149.
Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.
Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: light purple
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Vapor Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: 257 deg F
Freezing/Melting Point:117 deg F
Autoignition Temperature:
Not applicable.
Flash Point: Not applicable.
Decomposition
Temperature:100 deg C
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not
available.
Solubility: Soluble in water.
Specific
Gravity/Density:1.6840 (water)
Molecular Formula:FeN3O9.9H2O
Molecular Weight:403.9823
Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable. However, may decompose if heated.
Conditions to
Avoid: Incompatible materials, temperatures above 50�C.
Incompatibilities with Other Materials: Combustible materials,
reducing agents, strong oxidizing agents, light.
Hazardous Decomposition
Products: Nitrogen oxides.
Hazardous Polymerization: Has not been
reported.
Section 11 -
Toxicological Information |
RTECS#:
CAS# 7782-61-8: NO7175000
LD50/LC50:
CAS#
7782-61-8:
Oral, rat: LD50 = 3250 mg/kg;
Carcinogenicity:
CAS# 7782-61-8: Not listed by ACGIH, IARC, NIOSH,
NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive
Effects: No information available.
Neurotoxicity: No information
available.
Mutagenicity: No information available.
Other
Studies: None.
Section 12 -
Ecological Information |
Ecotoxicity: No
data available. No information available.
Environmental: No
information reported.
Physical: No information available.
Other: None.
Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 -
Transport Information |
|
US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
Shipping Name: |
FERRIC NITRATE |
|
|
|
FERRIC NITRATE |
Hazard Class: |
5.1 |
|
|
|
5.1(9.2) |
UN Number: |
UN1466 |
|
|
|
UN1466 |
Packing Group: |
III |
|
|
|
III |
Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 7782-61-8 is not listed on the
TSCA inventory. It is for research and development use only.
Health &
Safety Reporting List
None of the chemicals are on the Health &
Safety Reporting List.
Chemical Test Rules
None of the chemicals
in this product are under a Chemical Test Rule.
Section 12b
None
of the chemicals are listed under TSCA Section 12b.
TSCA Significant New
Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this
material have an RQ.
Section 302 (TPQ)
None of the chemicals in
this product have a TPQ.
SARA Codes
CAS # 7782-61-8: acute,
flammable, reactive.
Section 313
No chemicals are reportable under
Section 313.
Clean Air Act:
This material does not contain any
hazardous air pollutants. This material does not contain any Class 1 Ozone
depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed
as Hazardous Substances under the CWA. None of the chemicals in this product are
listed as Priority Pollutants under the CWA. None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None
of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7782-61-8 is not present on state lists from CA, PA,
MN, MA, FL, or NJ.
California No Significant Risk Level: None of the
chemicals in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
XI O
Risk Phrases:
R
36/37/38 Irritating to eyes, respiratory system
and skin.
R 8 Contact
with combustible material may cause
fire.
Safety
Phrases:
S 17 Keep away from combustible material.
S 24/25 Avoid
contact with skin and eyes.
WGK (Water Danger/Protection)
CAS#
7782-61-8: 1
Canada
Canada
None of the chemicals in
this product are listed on the DSL or NDSL list. This product has a WHMIS
classification of C, D2B.
CAS# 7782-61-8 is not listed on Canada's
Ingredient Disclosure List.
Exposure Limits
CAS# 7782-61-8:
OEL-DENMARK:TWA 1 mg(Fe)/m3 JANUARY 1993 OEL-FINLA
ND:TWA 1 mg(Fe)/m3 JANUARY
1993 OEL-THE NETHERLANDS:TWA 1 mg(Fe)/m3
JANUARY 1993 OEL-SWITZERLAND:TWA 1
mg(Fe)/m3 JANUARY 1993 OEL-UNIT
ED KINGDOM:TWA 1 mg(Fe)/m3;STEL 2 mg(Fe)/m3
JANUARY 1993
Section 16 -
Additional Information |
MSDS Creation Date:
9/02/1997
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.