KOCK REFINING CO INC -- GASOLINE, LEADED/UNLEADED (ALL GRADES) -- 9130-01-207-7039 
=====================  Product Identification  =====================

Product ID:GASOLINE, LEADED/UNLEADED (ALL GRADES)
MSDS Date:03/01/1988
FSC:9130
NIIN:01-207-7039
=== Responsible Party ===
Company Name:KOCK REFINING CO INC
Address:SUNTIDE RD
Box:2608
City:CORPUS CHRISTI
State:TX
ZIP:78403
Country:US
Info Phone Num:512-241-4811 / FAX 512-289-8470
Emergency Phone Num:512-241-4811
Preparer's Name:DALE F. JANES
CAGE:KO284
=== Contractor Identification ===
Company Name:KOCH REFINING CO INC
Address:SUNTIDE RD
Box:2608
City:CORPUS CHRISTI
State:TX
ZIP:78403
Country:US
Phone:512-241-4811
CAGE:3V260
Company Name:KOCK REFINING CO INC
Address:SUNTIDE RD
Box:2608
City:CORPUS CHRISTI
State:TX
ZIP:78403
Country:US
Phone:512-241-4811 / FAX 512-289-8470
CAGE:KO284

=============  Composition/Information on Ingredients  =============

Ingred Name:GASOLINE - PRODUCT MIXTURE CONTAINING THE FOLLOWING
    HAZARDOUS INGREDIENTS.
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM/500 STEL
ACGIH TLV:300 PPM/500STEL;9293

Ingred Name:PARAFFINS (MIX)
Fraction by Wt: 46%
Other REC Limits:NONE RECOMMENDED

Ingred Name:OLEFIN(S)
CAS:68425-39-8
Fraction by Wt: 17%
Other REC Limits:NONE RECOMMENDED

Ingred Name:NAPHTHENES
Fraction by Wt: 8%
Other REC Limits:100 PPM

Ingred Name:BENZENE  (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 1.5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9293
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:AROMATICS (OTHER)
Fraction by Wt: 27%
Other REC Limits:100 PPM

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5G/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:YES
Health Hazards Acute and Chronic:INHALATION: MODERATE RISK OF VAPOR
    INTOXICATION. MAJOR RISK IS ENCLOSED SPACES WITH POOR VENTILATION.
    SKIN: DEFATTING WITH DRYING AND CRACKING CAN LEAD TO DERMATITIS AND
    SECONDARY INFECTION. EYE: IRRI TANT. INGESTION: BURNING OF MOUTH
    AND UPPER GI TRACT, VOMITING AND DIARRHEA. PROLONGED OR REPEATED
    CONTACT: DERMATITIS.
Explanation of Carcinogenicity:CONTAINS B	[71-43-2] WHICH IS
    LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:INHALATION MAY CAUSE EUPHORIA, LUNG IRRITATION
    AND EDEMA, HEADACHE, DIZZINESS, DROWSINESS, CONVULSIONS, COMA,
    CYANOSIS, GENERALIZED DEPRESSION. INGESTION MAY CAUSE GENERAL
    DEPRESSION, SEDATION, RESPIR ATORY DEPRESSION, COMA.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING
    DERMATITIS, RESPIRATORY ILLNESS, OR OTHER CONDITIONS WHICH HAVE THE
    SAME SYMPTOMS OR EFFECTS AS STATED ABOVE.

=======================  First Aid Measures  =======================

First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING
    EYELIDS OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH
    SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. FOR RESPIRATORY
    DISTRESS,  GIVE AIR, OXYGEN, OR CPR IF NECESSARY. INGESTION: DO NOT
    INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS TO PREVENT
    ASPIRATION INTO LUNGS. GET MEDICAL ATTENTION IF REQUIRED IN ALL
    CASES.

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:-40F,-40C
Autoignition Temp:Autoignition Temp Text:>536F
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, FOAM, OR DRY
    CHEMICAL.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES, BUT SHOULD
    BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL. WATER SPRAY MAY BE
    USED TO FLUSH SPILL AWAY FROM AREAS OF IGINTION.
Unusual Fire/Explosion Hazard:HIGHLY VOLATILE MATERIAL. FLOWING
    GASOLINE CAN BE IGNITED BY SELF-GENERATED STATIC ELECTRICITY.
    VAPORS MAY TRAVEL ALONG THE GROUND TO A REMOTE IGNITION SOURCE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:SMALL: TAKE UP WITH NON COMBUSTIBLE ABSORBENT
    SUCH AS FULLERS EARTH OR SAND. PLACE INTO CONTAINERS FOR LATER
    DISPOSAL. LARGE: CONTAIN SPILL IN EARTHEN DIKES FOR LATER RECOVERY.
    CONTROL IGNITION SOURCE S AROUND SPILL AREA. REPORT SPILLS AS
    REQUIRED.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID STATIC IGNITION HAZARD WHEN
    TRANSFERRING MATERIAL. KEEP CONTAINERS CLOSED AND AWAY FROM HEAT &
    IGNITION SOURCES! DO NOT USE AS CLEANING AGENT.
Other Precautions:EMPTY CONTAINERS RETAIN SOME LIQUID/VAPOR RESIDUES;
    HAZARD PRECAUTIONS MUST BE OBSERVED WHEN HANDLING EMPTIES. KEEP OUT
    OF REACH OF CHILDREN! DO NOT USE ANY HYDROCARBON FUEL IN SPACES
    WITHOUT ADEQUATE  VENTILATION. USE ONLY AS A FUEL.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:A NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR,
    SUPPLIED AIR, OR SELF-CONTAINED BREATHING APPARATUS (SCBA) MUST BE
    USED WHEN VAPOR CONCENTRATIONS EXCEED THE OCCUPATIONAL EXPOSURE
    LIMITS.
Ventilation:USE ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF
    THIS MATERIAL BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:WEAR OIL IMPERVIOUS (EG: NITRILE) GLOVES
Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:OIL IMPERVIOUS INDUSTRIAL WORK CLOTHING TO
    MINIMIZE SKIN CONTACT. EYE BATH AND SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. USE WATERLESS HAND
    CLEANER TO WASH EXPOSED SKIN. LAUNDER CONTAMINATED CLOTHING BEFORE
    REUSE.
Supplemental Safety and Health
THE VARIABLE COMPOSITION MAKES IT IMPOSSIBLE TO SET A SPECIFIC EXPOSURE
    LIMIT FOR ALL COMPOSITIONS OF THIS MATERIAL. SPECIFIC EXPOSURE
    LIMITS FOR POTENTIAL COMPONENTS SUCH AS BENZENE SHOULD BE APPLIED 
    BASED ON AIR MONITORING TO ASSURE EMPLOYEES ARE NOT EXPOSED TO
    EXCESSIVE VAPOR LEVELS OF COMPONENTS.

==================  Physical/Chemical Properties  ==================

HCC:F1
Boiling Pt:B.P. Text:>85F,>29C
Melt/Freeze Pt:M.P/F.P Text:-130F,-90C
Vapor Pres:360-720
Vapor Density:3-4
Spec Gravity:0.72-0.76
pH:7
Evaporation Rate & Reference:MODERATELY FAST
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS LIQUID; GASOLINE ODOR
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
    OF IGNITION
Hazardous Decomposition Products:BURNING OR EXCESSIVE HEATING MAY
    PRODUCE CARBON MONOXIDE AND OTHER HARMFUL GASES/VAPORS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE USER TO
    DETERMINE IF THE MATERIAL IS A HAZARDOUS WASTE AT THE TIME OF
    DISPOSAL. CHECK BEFORE DISPOSING TO BE SURE YOU ARE IN COMPLIANCE
    WITH ALL APPLICABLE LAWS AND REG ULATIONS. CHEMTREC/RCRA EMER.
    NO.:800-424-9346

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