E I DUPONT DE NEMOURS & CO INC -- NASON PAINT PRODUCTS 419-64 -- -
===================== Product Identification ===================== Product ID:NASON PAINT PRODUCTS 419-64 MSDS Date:01/01/1999 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:E I DUPONT DE NEMOURS & CO INC Address:1007 MARKET ST City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-338-8083 Emergency Phone Num:800-441-3637 Resp. Party Other MSDS Num.:28 Chemtrec Ind/Phone:(800)424-9300 CAGE:18873 === Contractor Identification === Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:BUTYL ACETATE; VP: 8.0 MM HG @ 20C CAS:123-86-4 RTECS #:AF7350000 Other REC Limits:N/K OSHA PEL:710 MG/M3;150 PPM OSHA STEL:N/K ACGIH TLV:713 MG/M3;150 PPM ACGIH STEL:950 MG/M3;200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE; VP: 36.7 MM HG @ 20C CAS:108-88-3 RTECS #:XS5250000 = Wt:2. Other REC Limits:N/K OSHA PEL:SEE TABLE Z-2 OSHA STEL:N/K ACGIH TLV:188 MG/M3;50 PPM ACGIH STEL:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VM&P NAPHTHA; VP: 15 MM HG @ 37.8C CAS# 64742-89-8 Other REC Limits:N/K OSHA PEL:300 PPM OSHA STEL:400 PPM ACGIH TLV:300 PPM ACGIH STEL:400 PPM Ingred Name:XYLENE; VP: 7.0 MM HG @ 25C CAS:1330-20-7 RTECS #:ZE2100000 = Wt:2. Other REC Limits:N/K OSHA PEL:100 PPM OSHA STEL:150 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MEDIUM ALIPHATIC SOLVENT NAPHTHA (PETROLEUM): (MEDIUM MINERAL SPIRITS); VP:10.0 MM HG @ 20C CAS:64742-88-7 Ingred Name:ALKYD RESIN-F; VP: NONE @ 20C CAS:66070-93-7 Ingred Name:ALKYD RESIN-G; VP: NONE @ 20C CAS:67783-08-8 Ingred Name:TITANIUM DIOXIDE; VP: NONE @ 20C CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:GEN EFTS: INGEST: GI DISTRESS. INHAL: MAY CAUSE NOSE & THROAT IRRIT. RPTD & PRLNG OVEREXP TO SOLVS MAY LEAD TO PERM BRAIN & NERV SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ & LOSS OF COORD ARE SIGNS THAT SOLV LEVELS ARE TOO HIGH. ADDNL EFTS WHEN THIS MATL CONTAINS/IS MIXED W/ISOCYANATE ACTIVATOR/HARDENER: EXPOS TO ISOCYANATES MAY CAUSE RESP SENSIT. THIS EFT MAY BE PERM. THIS EFT MAY BE DELAYED FOR SEV ERAL HRS AFTER EXPOS. RPTD OVEREXP TO ISOCYANATES MAY CAUSE DECR IN LUNG FUNC WHICH MAY BE PERM. EYES: MAY CAUSE IRRIT/BURNING. SKIN: RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT W/DISCOMFORT & DERM. (EFTS OF OVEREXP) Effects of Overexposure:HEALTH HAZ: TOLUENE APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. CONSULT APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE I NFORMATION . SPECIFIC EFFECTS: VM & P NAPHTHA/ MEDIUM MINERAL SPIRITS: LABORATORY STUDIES WITH RATS HAVE SHOWN THAT PETROLEUM DISTILLATES CAN CAUSE KIDNEY DAMAGE & KIDNEY OR LIVER TUMORS. THESE EFFECTS WERE NOT SEEN IN SIMILAR STUDIES WITH GUINEA PIGS, (TOXICOLOGICAL INFO) Medical Cond Aggravated by Exposure:INDIVIDUALS W/BRTHG PROBLEMS/PRIOR RXN TO ISOCYANATES MUST NOT BE EXPOSED TO VAPS/SPRAY MISTS OF THIS PROD. INDIVIDUALS W/PREEXISTING DISEASES OF CNS, LUNGS, LIVER/KIDNEYS MAY HAVE INCRD (SARA REGS) ======================= First Aid Measures ======================= First Aid:INGESTION: IN THE UNLIKELY EVENT OF INGESTION, CALL A PHYSICIAN IMMEDIATELY AND HAVE THE NAMES OF THE INGREDIENTS AVAILABLE. DO NOT INDUCE VOMITING. INHALATION: IF AFFECTED BY INHALATION OF VAPOR OR S PRAY MIST, REMOVE TO FRESH AIR. IF BREATHING DIFFICULTY PERSISTS OR OCCURS LATER, CONSULT A PHYSICIAN. EYES: IN CASE EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES; CALL A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. IF IRRITATION OCCURS, CONTACT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>-6.7C, 20.F 20F - 73F Lower Limits:0.7% Upper Limits:23.0% Extinguishing Media:UNIVERSAL AQUEOUS FILM-FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP. Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS FLAMMABLE VAPORS WHICH, WHEN MIXED WITH AIR, CAN BURN OR BE EXPLOSIVE. FINE MISTS OR SPRAYS MAY BE FLAMMABLE AT TEMPERATURES BELOW THE FLASH POINT. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA. REMOVE IGNIT SOURCES. PVNT SKIN & EYE CONT & BRTHG OF VAP. WEAR NIOSH APPRVD RESP, EYE PROT, GLOVES & PROT CLTHG. CONFINE & REMOVE W/INERT ABSORB. IF MATL CONTAINS/IS MIXED W/ISOCYANATE ACT IVATOR/HARDENER: WEAR POS-PRESS, SUPP-AIR RESP (NIOSH APPRVD TC-19C). POUR LIQ DECONTAM SOLN OVER SPILL & ALLOW TO SIT AT LEAST 10 MINS. TYPICAL DECONTAM SOLNS FOR ISOCYANATES-CONTAINING (FED REGS) ====================== Handling and Storage ====================== Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINERS WHEN POURING. DO NOT STORE ABOVE 120F. OSHA STORAGE: IB. Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING WITHOUT A NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WHEN PRODS ARE USED W/PAINTS REQUIRING ISOCYANATE ACTIVATORS/HARDENERS, WEAR POS-PRESS, SUPP-AIR RESP (NIOSH APPRVD TC-19C) WHILE MIXING ACTIVATOR/HARDENER W/PAINT, DURING A PPLICATION & UNTIL ALL VAPS & SPRAY MISTS ARE EXHAUSTED. IF PROD IS USED W/OUT ISOCYANATE ACTIVATORS/HARDENERS, A PROPERLY FITTED AIR-PURIFYING (STATE REGS) Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO KEEP CONTAMINANTS BELOW APPLICABLE EXPOSURE LIMITS. Protective Gloves:NEOPRENE GLOVES ARE RECOMMENDED. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . COVERALLS ARE RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR SMOKING. Supplemental Safety and Health PHYSICAL/CHEM PROPERTIES: GAL WT (#/GAL): 6.66-13.03; WT % VOLAT: 9.68%-100%; GAL WT:8.31; WT PCT SOLIDS:46.09; VOL PCT SOLIDS: 31.38; SOLV DENSITY:6.53; VOC LE: 4.5; VOC AP: 4.5. ================== Physical/Chemical Properties ================== Boiling Pt:>26.C, 78.8F B.P. Text:26C - 900C Vapor Pres:SEE INGREDIENTS Vapor Density:HVR/AIR Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:MISCIBLE Percent Volatiles by Volume:12.5% - 100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES OF HEAVY METALS IN INGREDIENTS SECTION. =================== Toxicological Information =================== Toxicological Information:OVEREXPOSURE: DOGS OR MONKEYS. SEVERAL STUDIES EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN A SIGNIFICANT INCREASE OF KIDNEY DMG OR AN INCREASE IN KIDNEY OR LIVER TUMORS. TOLUENE: RECURRENT OVEREXP MA Y RESULT IN LIVER & KIDNEY INJURY. HIGH AIRBORNE LEVELS HAVE PRODUCED IRREG HEARTBEATS IN ANIMALS & OCCASIONAL PALPITATIONS IN HUMANS. RATS EXPOSED TO VERY HIGH AIRBORNE LEVELS HAVE EXHIBITED HIGH FRE Q HEARING DEFICITS. SIGNIFICANCE OF THIS TO MAN IS UNKNOWN. CHROMOSOMAL CHANGES IN CIRCULATING BLOOD OF EXPOSED WORKERS HAVE BEEN REPORTED. SIGNIFICANCE OF THESE RPTS IS UNCLEAR BECAUSE OF EXPOS TO OT HER SUBSTANCES. (ECOLOGICAL INFO) ===================== Ecological Information ===================== Ecological:TOX INFO: XYLENE: RECURRENT OVEREXPOSURE MAY RESULT IN LIVER & KIDNEY INUURY. CAN BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. INDIVIDUALS W/PRE-EXISTING DISEASE OF THE CENTRAL NERVOUS SYSTEM, KIDNEY S, LIVER, CARDIOVASCULAR SYSTEM, LUNGS OR BONE MARROW MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. CANADA CLASSIFIES XYLENE AS A DEVELOPMENTAL TOXIN AS HIGH EXPOSURES TO X YLENES IN SOME ANIMAL STUDIES HAVE BEEN REPORTED TO CAUSE HEALTH EFFECTS ON THE DEVELOPING FETUS/EMBRYO. THESE EFFECTS WERE OFTEN AT LEVELS TOXIC TO THE ADULT ANIMAL. THE SIGNIFICANCE OF THESE EFFECTS TO HUMANS IS NOT KNOWN. (OTHER INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS. ===================== Regulatory Information ===================== SARA Title III Information:THE FOLLOWING CHEMICALS ARE SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF EMERGENCY PLANNING & RIGHT-TO-KNOW ACT OF 1986 & OF 40 CFR 372: TOLUENE & XYLENE. MEDICAL CONDITIONS: SUSCEPTIBILITY T O TOXICITY OF EXCESS EXPOSURE. INDIVIDUALS WITH PREEXISTING DISEASES OF KIDNEYS, LIVER, CARDIOVASCULAR SYSTEM BONE MARROW MAY HAVE INCREASED SUSCEPTIBILITY TO TOXICITY OF EXCESS EXPOSURE. Federal Regulatory Information:SPILL PROC: MATERIALS ARE: 20% SURFACTANT (TERGITOL TMN 10) & 80% WATER OR 0-10% AMMONIA, 2-5% DETERGENT & WATER (BALANCE). PRESS CAN BE GENERATED. DO NOT SEAL CONTAINER. AFTER 48 HOURS, MATERIAL MAY BE SEALED & DISPOSED OF PROPERLY. IF MATERIAL DOES NOT CONTAIN/IS NOT MIXED WITH ISOCYANATE ACTIVATOR/HARDENER: WEAR PROPERLY FITTED AIR-PURIFYING RESP WITH ORGANIC VAPOR CARTRIDGES (NIOSH APPRVD TC- 23C). State Regulatory Information:WARNING: TOLUENE IS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. RESP PROT: RESPIRATOR W/ORGANIC VAPOR CARTRIDGES (NIOSH TC-23C) & PARTICULATE FILTER (NIOSH TC-8 4A) MAY BE USED. FOLLOW RESP MFR'S DIRECTIONS FOR RESP USE. DO NOT PERMIT ANYONE W/OUT PROTECTION IN PAINTING AREA. REFER TO HARDENER/ACTIVATOR LABEL INSTRUCTIONS & MSDS FOR FURTHER INFORMATION. PERSO NS WITH HISTORY OF LUNG/BREATHING PROBLEMS/PRIOR REACTION TO ISOCYANATES SHOULD NOT USE/BE EXPOSED T O PRODUCT IF MIXED WITH ISOCYANATE ACTIVATORS/HARDENERS. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.