KEMIRON INC -- FERRIC SULFATE SOLUTION -- 6810-00F054358
===================== Product Identification ===================== Product ID:FERRIC SULFATE SOLUTION MSDS Date:04/01/1997 FSC:6810 NIIN:00F054358 === Responsible Party === Company Name:KEMIRON INC Address:316 BARTOW MUNICIPAL AIRPORT City:BARTOW State:FL ZIP:33830-5000 Country:US Info Phone Num:941-533-5990 Emergency Phone Num:941-533-5990 Preparer's Name:FRED D SIMS JR CAGE:09BE9 === Contractor Identification === Company Name:KEMIRON INC Address:316 BARTOW MUNICIPAL AIRPORT City:BARTOW State:FL ZIP:33830-5000 Country:US Phone:941-533-5990 CAGE:09BE9 ============= Composition/Information on Ingredients ============= Ingred Name:FERRIC SULFATE *97-2* CAS:10028-22-5 RTECS #:NO8505000 Fraction by Wt: 35-45% OSHA PEL:2 MG/CUM ACGIH TLV:1 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 55-65% Ingred Name:SULFURIC ACID (CONFIRMED HUMAN CARCINOGEN BY IARC - GROUP 1) *97-2* CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: <0.2% OSHA PEL:1 MG/CUM ACGIH TLV:1 MG/CUM=IC EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RABBIT): 2140 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: MUCOUS MEMBRANES, RESPIRATORY TRACT & LUNG TISSUE IRRITATION. INGESTION: STOMACH IRRITATION, DIGESTIVE TRACT BURNS, LIVER CIRRHOSIS & FIBROSIS OF PANCREAS. SKIN: IRRITATION, DERMATITIS, BU RNS, HIGHLY TOXIC BY IV. EYES: CORROSIVE, SEVERE IRRITATION, BURNS TO MUCOUS MEMBRANE LINING OF INNER EYELID SURFACES. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, BURNS, ALTERED RESPIRATORY RATE, SOMNOLENCE, DIARRHEA, TACHYCARDIA, HEMATEMESIS (VOMITING BLOOD). ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: DRINK LARGE AMOUNTS OF WATER/MILK TO REDUCE CONCENTRATION & NEUTRALIZE MATERIAL. DON'T INDUCE VOMITING. IF UNCONSCIOUS, DO NOTHIN G & KEEP WARM. SKIN: FLUSH W/WATER FOR 15 MINS. THOROUGHLY WASH AFFECTED AREAS W/SOAP & WATER. EYES: IMMEDIATELY IRRIGATE W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CO2, DRY CHEMICALS. Fire Fighting Procedures:WEAR A SCBA/RESPIRATOR W/APPROPRIATE CARTRIDGES. Unusual Fire/Explosion Hazard:NOT CONSIDERED A FIRE/EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE AREA IF POSSIBLE. NEUTRALIZE. Neutralizing Agent:LIME, SODA ASH/SODIUM BICARBONATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:MAY BE SAFELY STORED IN FIBERGLASS, PLASTICS, RUBBER/TYPE 316/BETTER GRADES OF STEEL. WEAR APPROPRIATE SAFETY GEAR WHEN HANDLING MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO RESPIRATOR IS REQUIRED UNDER NORMAL CONDITIONS OF USE. WEAR A NIOSH APPROVED DUST/MIST RESPIRATOR IF TLV IS EXCEEDED. ALTERNATIVELY, A SCBA/SUPPLIED AIR FULL FACEPIECE RESPIRATOR MAY BE WORN. Protective Gloves:RUBBER/NEOPRENE Eye Protection:CHEMICAL SAFETY GOGGLES Other Protective Equipment:RUBBER BOOTS/SAFETY SHOES, EYE WASH FOUNTAIN Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING. Supplemental Safety and Health PH (APPARENT): <1; PH (1% SOLUTION): 1.84 ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Melt/Freeze Pt:M.P/F.P Text:-50F Spec Gravity:1.4-1.57 pH:(SUPP) Solubility in Water:COMPLETE Appearance and Odor:DARK REDDISH BROWN SOLUTION W/SLIGHT, MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAST IRON/BRONZE, BRASS, 304SS, HASTELLOY B, COPPER & ALLOYS, GALVANIZED STEEL, ALUMINUM, PAINTS, ENAMELS, CONCRETE. Stability Condition to Avoid:HIGH TEMPS, OPEN FLAMES. Hazardous Decomposition Products:BY HEATING TO DECOMPOSITION: TOXIC SULFUR OXIDE & IRON FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:REMOVE WASTE TO AN APPROVED LANDFILL/WASTE DISPOSAL FACILITY IAW/FEDERAL, STATE & LOCAL REGULATIONS. CORROSIVE LIQUID UN3264. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.